| Titre : | High-temperature Solid Oxide Fuel Cells : fundamentals, Design and Applications | | Type de document : | texte imprimé | | Auteurs : | Subhash Singhal, Auteur ; Kevin Kendall, Auteur | | Editeur : | Kidlington, Amsterdam, The Netherlands : Elsevier | | Année de publication : | 2003 | | Importance : | 405 p. | | Présentation : | couv. ill. en coul. | | Format : | 24 cm. | | ISBN/ISSN/EAN : | 9781856173879 | | Langues : | Anglais (eng) | | Index. décimale : | 05-05 Thermodynamique | | Résumé : | High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information.
The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level. | | Note de contenu : | Table of Contents
Chapter 1 Introduction to SOFCs
Chapter 2 History
2.1 The Path to the First Solid Electrolyte Gas Cells
2.2 From Solid Electrolyte Gas Cells to Solid Oxide Fuel Cells
2.3 First Detailed Investigations of Solid Oxide Fuel Cells
2.4 Progress in the 196Os
2.5 On the Path to Practical Solid Oxide Fuel Cells
Chapter 3 Thermodynamics
3.2 The Ideal Reversible SOFC
3.3. Voltage Losses by Ohmic Resistance and by Mixing Effects by Fuel Utilisation
3.4 Thermodynamic Definition of a Fuel Cell Producing Electricity and Heat
3.5 Thermodynamic Theory of SOFC Hybrid Systems
3.6 Design Principles of SOFC Hybrid Systems
Chapter 4 Electrolytes
4.2 Fluorite-Structured Electrolytes
4.3 Zirconia-Based Oxide Ion Conductors
4.4 Ceria-Based Oxide Ion Conductors
4.5 Fabrication of ZrO2 and CeO2-Based Electrolyte Films
4.6 Perovskite-Structured Electrolytes
4.7 Oxides with Other Structures
4.8 Proton-Conducting Oxides
Chapter 5 Cathodes
5.2 Physical and Physicochemical Properties of Perovskite Cathode Materials
5.3 Reactivity of Perovskite Cathodes with ZrO2
5.4 Compatibility of Perovskite Cathodes with Interconnects
5.5 Fabrication of Cathodes
Chapter 6 Anodes
6.2 Requirements for an Anode
6.3 Choice of Cermet Anode Components
6.4 Cermet Fabrication
6.5 Anode Behavior under Steady-State Conditions
6.6 Anode Behavior under Transients Near Equilibrium
6.7 Behavior of Anodes under Current Loading
6.8 Operation of Anodes with Fuels Other Than Hydrogen
6.9 Anodes for Direct Oxidation of Hydrocarbons
Chapter 7 Interconnects
7.2 Ceramic Interconnects (Lanthanum and Yttrium Chromites)
7.3 Metallic Interconnects
7.4 Protective Coatings and Contact Materials for Metallic Interconnects
Chapter 8 Cell and Stack Designs
8.2 Planar SOFC Design
8.3 Tubular SOFC Design
8.4 Microtubular SOFC Design
Chapter 9. Electrode Polarizations
9.2 Ohmic Polarization
9.3 Concentration Polarization
9.4 Activation Polarization
9.5 Measurement of Polarization (By Electrochemical Impedance Spectroscopy)
Chapter 10 Testing of Electrodes, Cells and Short Stacks
10.2 Testing Electrodes
10.3 Testing Cells and 'Short' Stacks
10.4 Area-Specific Resistance (ASR)
10.5 Comparison of Test Results on Electrodes and on Cells
10.6 The Problem of Gas Leakage in Cell Testing
Chapter 11 Cell, Stack and System Modeling
11.2 Flow and Thermal Models
11.3 Continuum-Level Electrochemistry Model
11.4 Chemical Reactions and Rate Equations
11.5 Cell- and Stack-Level Modeling
11.6 System-Level Modeling
11.7 Thermomechanical Model
11.8 Electrochemical Models at the Electrode Level
11.9 Molecular-Level Models
Chapter 12 Fuels and Fuel Processing
12.2 Range of Fuels
12.3 Direct and Indirect Internal Reforming
12.4 Reformation of Hydrocarbons by Steam, CO2 and Partial Oxidation
12.5 Direct Electrocatalytic Oxidation of Hydrocarbons
12.6 Carbon Deposition
12.7 Sulfur Tolerance and Removal
12.8 Anode Materials in the Context of Fuel Processing
12.9 Using Renewable Fuels in SOFCs
Chapter 13 Systems and Applications
13.2 Trends in the Energy Markets and SOFC Applicability
13.3 Competing Power Generation Systems and SOFC Applications
13.4 SOFC System Designs and Performance
13.5 SOFC System Demonstrations
-Index |
High-temperature Solid Oxide Fuel Cells : fundamentals, Design and Applications [texte imprimé] / Subhash Singhal, Auteur ; Kevin Kendall, Auteur . - Kidlington, Amsterdam, The Netherlands : Elsevier, 2003 . - 405 p. : couv. ill. en coul. ; 24 cm. ISSN : 9781856173879 Langues : Anglais ( eng) | Index. décimale : | 05-05 Thermodynamique | | Résumé : | High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information.
The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level. | | Note de contenu : | Table of Contents
Chapter 1 Introduction to SOFCs
Chapter 2 History
2.1 The Path to the First Solid Electrolyte Gas Cells
2.2 From Solid Electrolyte Gas Cells to Solid Oxide Fuel Cells
2.3 First Detailed Investigations of Solid Oxide Fuel Cells
2.4 Progress in the 196Os
2.5 On the Path to Practical Solid Oxide Fuel Cells
Chapter 3 Thermodynamics
3.2 The Ideal Reversible SOFC
3.3. Voltage Losses by Ohmic Resistance and by Mixing Effects by Fuel Utilisation
3.4 Thermodynamic Definition of a Fuel Cell Producing Electricity and Heat
3.5 Thermodynamic Theory of SOFC Hybrid Systems
3.6 Design Principles of SOFC Hybrid Systems
Chapter 4 Electrolytes
4.2 Fluorite-Structured Electrolytes
4.3 Zirconia-Based Oxide Ion Conductors
4.4 Ceria-Based Oxide Ion Conductors
4.5 Fabrication of ZrO2 and CeO2-Based Electrolyte Films
4.6 Perovskite-Structured Electrolytes
4.7 Oxides with Other Structures
4.8 Proton-Conducting Oxides
Chapter 5 Cathodes
5.2 Physical and Physicochemical Properties of Perovskite Cathode Materials
5.3 Reactivity of Perovskite Cathodes with ZrO2
5.4 Compatibility of Perovskite Cathodes with Interconnects
5.5 Fabrication of Cathodes
Chapter 6 Anodes
6.2 Requirements for an Anode
6.3 Choice of Cermet Anode Components
6.4 Cermet Fabrication
6.5 Anode Behavior under Steady-State Conditions
6.6 Anode Behavior under Transients Near Equilibrium
6.7 Behavior of Anodes under Current Loading
6.8 Operation of Anodes with Fuels Other Than Hydrogen
6.9 Anodes for Direct Oxidation of Hydrocarbons
Chapter 7 Interconnects
7.2 Ceramic Interconnects (Lanthanum and Yttrium Chromites)
7.3 Metallic Interconnects
7.4 Protective Coatings and Contact Materials for Metallic Interconnects
Chapter 8 Cell and Stack Designs
8.2 Planar SOFC Design
8.3 Tubular SOFC Design
8.4 Microtubular SOFC Design
Chapter 9. Electrode Polarizations
9.2 Ohmic Polarization
9.3 Concentration Polarization
9.4 Activation Polarization
9.5 Measurement of Polarization (By Electrochemical Impedance Spectroscopy)
Chapter 10 Testing of Electrodes, Cells and Short Stacks
10.2 Testing Electrodes
10.3 Testing Cells and 'Short' Stacks
10.4 Area-Specific Resistance (ASR)
10.5 Comparison of Test Results on Electrodes and on Cells
10.6 The Problem of Gas Leakage in Cell Testing
Chapter 11 Cell, Stack and System Modeling
11.2 Flow and Thermal Models
11.3 Continuum-Level Electrochemistry Model
11.4 Chemical Reactions and Rate Equations
11.5 Cell- and Stack-Level Modeling
11.6 System-Level Modeling
11.7 Thermomechanical Model
11.8 Electrochemical Models at the Electrode Level
11.9 Molecular-Level Models
Chapter 12 Fuels and Fuel Processing
12.2 Range of Fuels
12.3 Direct and Indirect Internal Reforming
12.4 Reformation of Hydrocarbons by Steam, CO2 and Partial Oxidation
12.5 Direct Electrocatalytic Oxidation of Hydrocarbons
12.6 Carbon Deposition
12.7 Sulfur Tolerance and Removal
12.8 Anode Materials in the Context of Fuel Processing
12.9 Using Renewable Fuels in SOFCs
Chapter 13 Systems and Applications
13.2 Trends in the Energy Markets and SOFC Applicability
13.3 Competing Power Generation Systems and SOFC Applications
13.4 SOFC System Designs and Performance
13.5 SOFC System Demonstrations
-Index |
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